
Microcement is a multi-functional and innovative decorative cement-based coating. Due to its thin application depth and high adhesion, it can be applied to different substrates (floors, walls, façades) as a surface finishing coat. Sometimes known as microconcrete or microtopping, microcement consists of a mixture of cement (usually grey or white), very fine aggregates, various polymer resins, and additives. Thanks to its high design flexibility and seamless, joint-free finish, this material has achieved substantial popularity as a rehabilitation solution, as well as for decoration of interiors and exteriors.
Microcement is arguably one of the most significant design advantages for the development of robust adhesion to almost any substrate, enabling application to concrete, tiles, timber, or even existing coatings. From this adhesion and continuity, microcement is left with a hard surface for decorative applications to the degree that high-quality products and correct application would exhibit high resistance to cracking, abrasion, and impact. The combination of these performance characteristics, with a modern and continuous aesthetic finish, has earned micro cement significant popularity in the architectural and interior/exterior design space.
Microcement is supplied as a multiple component system, where each component fulfills a specific technical role. The main one is cement, as the mineral binder with hardening properties. The mix contains very fine mineral fillers (such as stone powder, silica, or calcium carbonate) to help ensure consistency and reduce shrinkage and cracking. One of the other main components is resin, usually as water-based acrylic, as an organic binder and modifier. The addition of acrylic resin also enhances adhesion to the substrate and resilience, thanks to its flexibility within the cement matrix. There will be a range of additives such as plasticizers for workability, setting time regulators, mineral pigments if a range of colors is desired, and sometimes fibers or other microstructure modifiers. The exact formulation of microcement has been adjusted by manufacturers depending on the intended final application, but in general terms we can say that microcement is a cement–polymer composite made from these components.

From a materials science perspective, the addition of polymer resins such as acrylic resin to cement mixes genuinely improve their aesthetics, mechanical performance, and durability. There is ample evidence that resin improves the compressive strength and significantly enhances the tensile and flexural strength. The resulting material is more ductile and tougher. An experimental study showed that with only 3% polymer blended into cement mortar, the flexural strength increased by as much as 63% compared to that of the unmodified sample. The role of the polymer in improving flexural resistance and stiffness, and decreasing the brittleness of the matrix cannot be overstated.
Further, the polymer reinforces the bond between the new microcement layer, and the existing substrate material, and altogether creates an enormous increase in adhesion at the interface. Technical reports affirm that water-based acrylic resin will notably enhance the adhesion of the surface to the substrate, while providing a structural internal cohesion, and improving tensile, compressive, and flexural strength. All of these improvements affirm that acrylic resin is serving as a very effective reinforcement in microcement, incorporating the benefits of an acrylic resin to counter the issues of brittleness and low adhesion associated with cement mortar.
Another important feature of acrylic resins is their flexibility and crack resistance in cement-based coatings. Once dry, the polymer particles create a continuous polymeric film in the cement, averting the continuation of microcracks. Put another way, acrylic resin develops polymer “bridges” in the cement matrix, effectively redistributing tensile stresses and permitting small amounts of deformation without cracking. On practical terms, acrylicwithstand crack problems and improve the elastic nature of mortars. Therefore, acrylic-modified microcement can withstand stresses, such as shrinkage stresses from drying or shifts in the substrate, without cracking, which greatly prolongs the life of the coating. The resources of flexibility also contributes to the increased resistance to impacts and vibration; most cement mortars are very brittle, whereas the polymer phase makes them much tougher.
Choosing the right polymer resin for a microcement system involves consideration of several important parameters that affect the actual performance of the coating:

Acrylic resins are an essential component in microcement and provide both aesthetic beauty and durability. Acrylic resin provides the ability to create a smooth or seamless finish that is accepted by architects while providing increased adhesion, flexibility, or durability for lasting performance. There are many technical and scientific studies proving that polymer modification of cement mortar can significantly modify performance. It is proven that microcement modified with acrylic can last for years even in harsh conditions without cracking while retaining adhesion and the surface appearance. In comparison to other resin-based systems, acrylic has a superior combination of properties yielding an efficient and versatile option for thin decorative coatings. For this reason, most of the scientific and industrial literature promotes the usage of acrylic latexes as modifiers in the cementitious mortars.
References
https://www.topciment.com/en-us/microcement
https://www.resinflooringcompany.com/the-ultimate-guide-to-the-microcement-materials
https://www.mdpi.com/2076-3417/10/3/1061
https://aqviz.com/waterproofing/methods/cementitious/types